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Dr. Torsten Gutmann, Dr. Iker del Rosal, Dr. Bruno Chaudret, Prof. Dr. Romuald Poteau, Prof. Dr. Hans-Heinrich Limbach and Prof. Dr. Gerd Buntkowsky From Molecular Complexes to Complex Metallic Nanostructures—2H Solid-State NMR Studies of Ruthenium-Containing Hydrogenation Catalysts ChemPhysChem 14

Version of Record online: 9 MAY 2013 | DOI: 10.1002/cphc.201300200

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D will do what H can't: An overview on advanced 2H solid-state NMR investigations combined with quantum-chemical calculations aimed at the study of structure and dynamics of deuterium/hydrogen in molecular complexes and clusters. This approach contributes to the understanding of the interaction of hydrogen with the surface of metal nanoparticles at the molecular level, as well as the mechanistic implications in catalytic reactions such as hydrogenation.

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