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Fang Zou, Runhan Yu, Rongguan Li and Prof. Wei Li Microwave-Assisted Synthesis of HKUST-1 and Functionalized HKUST-1-@H3PW12O40: Selective Adsorption of Heavy Metal Ions in Water Analyzed with Synchrotron Radiation ChemPhysChem 14

Version of Record online: 1 JUL 2013 | DOI: 10.1002/cphc.201300215

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Keggin' the pores: Metal-organic frameworks are promising pollutant adsorbents offering high selectivity and large adsorption capacity, although their stability in water turns industrial application questionable. An improved, expeditious microwave-assisted synthesis of HKUST-1 [Cu3(1,3,5-benzene-tri-carboxilic-acid)2], along with the introduction of a Keggin-type phosphotungstate is presented, resulting in an enhanced stability in water and a higher intake of heavy metal ions.

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