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Roman Meier, Prof. Danuta Kruk and Prof. Ernst A. Rössler Intermolecular Spin Relaxation and Translation Diffusion in Liquids and Polymer Melts: Insight from Field-Cycling 1H NMR Relaxometry ChemPhysChem 14

Version of Record online: 23 JUL 2013 | DOI: 10.1002/cphc.201300257

Thumbnail image of graphical abstract

Going through the motions: The time correlation function reflects molecular rotation as well as translation in liquids and polymers. The two contributions can be separated (see picture). The power law of the long-time tail of the correlation function gives direct access to the diffusion coefficient.

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