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Dr. Thierry Darmanin and Prof. Frederic Guittard pH- and Voltage-Switchable Superhydrophobic Surfaces by Electro-Copolymerization of EDOT Derivatives Containing Carboxylic Acids and Long Alkyl Chains ChemPhysChem 14

Article first published online: 29 MAY 2013 | DOI: 10.1002/cphc.201300283

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pH- and voltage-switchable superhydrophobic surfaces are obtained by electrodeposition of conducting polymers bearing carboxylic acids and dodecyl chains. The electrochemical reduction (voltage switch) allows the removal of the doping anions while the treatment with NaOH (pH switch) allows one to change the carboxylic groups into carboxylate groups.

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