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Dr. Luís Pinto da Silva, Dr. Ron Simkovitch, Prof. Dr. Dan Huppert and Prof. Dr. Joaquim C. G. Esteves da Silva Theoretical Photodynamic Study of the Photoprotolytic Cycle of Firefly Oxyluciferin ChemPhysChem 14

Article first published online: 13 JUN 2013 | DOI: 10.1002/cphc.201300330

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A pH-sensitive fluorophore: Different conformations of the π–π stacking complex of the excited-state enolate species of firefly oxyluciferin lead to pH-sensitive fluorescence. This means that the enolate anion possesses different emission energies at acidic/neutral and basic pH.

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