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Prof. Dr. Kasper P. Kepp O2 Binding to Heme is Strongly Facilitated by Near-Degeneracy of Electronic States ChemPhysChem 14

Version of Record online: 22 AUG 2013 | DOI: 10.1002/cphc.201300658

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Crossing borders: The paper reports how close-lying spin states and resulting broad crossing regions enable fast, reversible oxygen binding to heme (see picture), despite the small spin–orbit coupling of this biologically important spin-forbidden process.

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