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Dr. Kyung Hwan Kim, Hosung Ki, Key Young Oang, Prof. Shunsuke Nozawa, Dr. Tokushi Sato, Prof. Joonghan Kim, Prof. Tae Kyu Kim, Prof. Jeongho Kim, Prof. Shin-ichi Adachi and Prof. Hyotcherl Ihee Global Reaction Pathways in the Photodissociation of I3− Ions in Solution at 267 and 400 nm Studied by Picosecond X-ray Liquidography ChemPhysChem 14

Version of Record online: 2 OCT 2013 | DOI: 10.1002/cphc.201300713

Thumbnail image of graphical abstract

An eye for an I: By performing time-resolved X-ray liquidography measurements at two different excitation wavelengths, the wavelength dependence of the reaction mechanism of I3 photodissociation is elucidated (see picture). In addition to the reaction dynamics of solute species, the results reveal the transient structure of the solute/solvent cage and the changes in solvent density and temperature as a function of time.

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