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Dr. Guosheng Shi, Jinrong Yang, Prof. Yihong Ding and Prof. Haiping Fang Orbital Effect-Induced Anomalous Anion–π Interactions between Electron-Rich Aromatic Hydrocarbons and Fluoride ChemPhysChem 15

Version of Record online: 30 MAY 2014 | DOI: 10.1002/cphc.201402075

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Orbital attraction: An orbital effect-induced anomalous anion–π interaction between electron-rich π systems (aromatic hydrocarbons) and fluoride is reported. The anion–π interactions between fluoride and electron-rich π rings increase markedly with increasing number of π electrons and increasing size of the π rings.

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