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Dr. Ulrich Glebe, Prof. Tobias Weidner, Dr. Joe E. Baio, Dr. Denise Schach, Dr. Clemens Bruhn, Dr. Axel Buchholz, Prof. Winfried Plass, Dr. Stephan Walleck, Prof. Thorsten Glaser and Prof. Ulrich Siemeling Self-Assembled Monolayers of Single-Molecule Magnets [Tb{Pc′(SR)8}2] on Gold ChemPlusChem 77

Version of Record online: 13 JUL 2012 | DOI: 10.1002/cplu.201200043

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SMM SAMs: The magnetic properties of bis(phthalocyaninato)terbium(III) complexes [Tb{Pc′(SR)8}2] bearing eight peripheral alkylthio substituents SR (R=n-C8H17, n-C12H25; see figure) were studied by SQUID measurements. These highly soluble single-molecule magnets were self-assembled from solution onto solid gold substrates and the self-assembled monolayers characterised by XPS, NEXAFS and AFM measurements.

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