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Francesco Parrino, Ayyappan Ramakrishnan, Cornelia Damm and Prof. Dr. Horst Kisch Visible-Light-Induced Sulfoxidation of Alkanes in the Presence of Titania ChemPlusChem 77

Article first published online: 10 JUL 2012 | DOI: 10.1002/cplu.201200097

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Visible-light photosulfoxidation: Titanium dioxide photocatalyzes visible-light-induced sulfoxidation of alkanes through an optical charge-transfer excitation of a titania–sulfur dioxide complex (see proposed mechanism). The reaction exhibits typical features of a photoinduced radical chain reaction.

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