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Juan Mancebo-Aracil, Dr. María J. Muñoz-Guillena, Ion Such-Basáñez and Dr. José M. Sansano-Gil Kinetic Study of Thermal 1,3-Dipolar Cycloaddition of Azomethine Ylides by Using Differential Scanning Calorimetry ChemPlusChem 77

Article first published online: 26 JUN 2012 | DOI: 10.1002/cplu.201200107

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The kinetics of the title cycloaddition has been evaluated through differential scanning calorimetry (DSC; see scheme, Bn=benzyl).The application of known kinetic models and mathematical multiple non-linear regressions allow the determination and comparison of Ea, lnA, reaction orders, and reaction enthalpy values. Finally a rate equation for each temperature studied can be established for this particular thermal cycloaddition.

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