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Prof. Dr. Mamoru Fujitsuka, Dr. Shingo Samori, Sachiko Tojo, Prof. Dr. Michael M. Haley and Prof. Dr. Tetsuro Majima Dimerization Reaction of Regioisomeric Bis(phenylethynyl)benzene Radical Anions during Pulse Radiolysis ChemPlusChem 77

Article first published online: 3 JUL 2012 | DOI: 10.1002/cplu.201200110

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Pulse radiolysis for dimerization: Dimerization of a series of regioisomeric 1,4-, 1,3-, and 1,2-bis(phenylethynyl)benzene radical anions substituted by various electron-donor and/or electron-acceptor groups was studied during pulse radiolysis (see scheme; DMF=N,N-dimethylformamide). The rate constant of dimerization depends largely on substitution pattern and electronic nature of substituents.

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