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Gangbing Zhu, Xiaohua Zhang, Pengbo Gai and Prof. Dr. Jinhua Chen Enhanced Electrochemical Sensing for Persistent Organic Pollutants by Nanohybrids of Graphene Nanosheets that are Noncovalently Functionalized with Cyclodextrin ChemPlusChem 77

Version of Record online: 9 JUL 2012 | DOI: 10.1002/cplu.201200144

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Bridging the gap: Using 3,4,9,10-perylene tetracarboxylic acid as a bridge to connect mono(6-ethanediamine-6-deoxy)-β-cyclodextrin to the surface of graphene, the nanohybrid material had been synthesized and used as sensing material for electrochemical detection of persistent organic pollutants (see figure, GC=glassy carbon). The limit of detection is 1.0 nM (S/N=3), and is at least eight times lower than for other electrochemical sensors.

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