Dr. Matteo Mannini, Dr. Stefano Cicchi, Dr. Debora Berti, Prof. Dr. Andrea Caneschi, Prof. Alberto Brandi, Dr. Luisa Lascialfari and Dr. Lorenzo Sorace Radical-Functionalised Gel: A Building-Block Strategy for Magnetochiral Assembly ChemPlusChem 78
A radically new gel: AFM and ESR spectroscopic studies are used to investigate a radical-functionalised gel and the gelation process (see graph). The analyses also provide evidence that the fibrillar structure is maintained below the gelling concentration. This opens relevant perspectives in terms of the realization of complex supramolecular chiral structures incorporating paramagnetic functions.
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