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Aleksey L. Mindich, Nadezhda A. Bokach, Maxim L. Kuznetsov, Matti Haukka, Andrey P. Zhdanov, Konstantin Yu. Zhizhin, Serguei A. Miltsov, Nikolay T. Kuznetsov and Vadim Yu. Kukushkin Coupling of Azomethine Ylides with Nitrilium Derivatives of closo-Decaborate Clusters: A Synthetic and Theoretical Study ChemPlusChem 77

Article first published online: 23 NOV 2012 | DOI: 10.1002/cplu.201200257

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Boron clusters: The first examples of a selective nucleophilic addition of pyridinium azomethine ylides to the nitrile group and of new C[BOND]C bond formation in the reaction of nitrilium derivatives of boron clusters with nucleophiles are presented. Theoretical considerations of plausible mechanisms and driving forces of the reactions were investigated in detail.

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