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Qiuju Yan, Yichao Lin, Dr. Pengyan Wu, Li Zhao, Lujie Cao, Prof. Luming Peng, Assoc. Prof. Chunlong Kong and Prof. Liang Chen Designed Synthesis of Functionalized Two-Dimensional Metal–Organic Frameworks with Preferential CO2 Capture ChemPlusChem 78

Article first published online: 21 NOV 2012 | DOI: 10.1002/cplu.201200270

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What a catch! A series of three functionalized metal–organic frameworks have been fabricated by the combination of direct synthesis (template-free) and covalent modification. The resulting frameworks display fairly good thermal stability and moisture resistance. Regardless of the moderate surface area, the grafted carbonyl functionalities enhance the selective CO2 adsorption capacity (see figure).

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