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Peng Cheng Wang, Jie Zhu, Xiang Liu, Ting Ting Lu and Prof. Ming Lu Regioselective Nitration of Aromatics with Nanomagnetic Solid Superacid SO42−/ZrO2-MxOy-Fe3O4 and Its Theoretical Studies ChemPlusChem 78

Version of Record online: 12 FEB 2013 | DOI: 10.1002/cplu.201300001

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Super acids: A series of micro- and nanosulfated zirconia loaded with Fe3O4 and other metal oxides (SO42−/ZrO2-MxOy-Fe3O4) have been prepared and characterized. Nitration experiments with these solid acids were carried out to achieve the optimal conditions and their performances were evaluated. By taking the nitration of chlorobenzene as an example, theoretical calculations were used to investigate the interaction between transition metals and chlorobenzene (see figure).

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