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Dr. Christian Maurer, Dr. Ernst Pittenauer, Dr. Michael Puchberger, Prof. Dr. Günter Allmaier and Prof. Dr. Ulrich Schubert Dioximate- and Bis(salicylaldiminate)-Bridged Titanium and Zirconium Alkoxides: Structure Elucidation by Mass Spectrometry ChemPlusChem 78

Article first published online: 27 FEB 2013 | DOI: 10.1002/cplu.201300014

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Building bridges: Modification of titanium and zirconium alkoxides with various dioximes and bis(salicylaldimines) resulted in dimeric complexes, in which the ligands bridge the metal alkoxide moieties (see figure; O red, N blue). ESI mass spectrometry was found to be a powerful tool for structure elucidation of the complexes.

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