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Prof. Dr. Anna Chrostowska, Prof. Alain Dargelos, Patrick Baylère, Prof. Alain Graciaa, Yusuke Inagaki, Dr. Masaaki Nakamoto, Dr. Vladimir Ya. Lee and Prof. Dr. Akira Sekiguchi UV-Photoelectron Spectroscopy of a Tetrakis(trimethylsilyl)tetrahedrane and Its Pentafluorophenyl Derivative ChemPlusChem 78

Version of Record online: 3 APR 2013 | DOI: 10.1002/cplu.201300044

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Strained cages: UV-photoelectron spectroscopy studies of tetrakis(trimethylsilyl)tetrahedrane and its pentafluorophenyl derivative (see figure) demonstrate the effectiveness of the neutral hyperconjugation in the latter, which was initially proposed on the basis of electronic spectra and computational data.

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