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Dr. Sneha R. Bajpe, Dr. Eric Breynaert, Ana Martin-Calvo, Dr. Danilo Mustafa, Prof. Sofia Calero, Prof. Christine E. A. Kirschhock and Prof. Johan A. Martens COK-16: A Cation-Exchanging Metal–Organic Framework Hybrid ChemPlusChem 78

Article first published online: 3 APR 2013 | DOI: 10.1002/cplu.201300080

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X-ray spectroscopy: Substoichiometric encapsulation of polyoxometalate ions into a metal–organic framework results in a fully functional cation exchanger with accessible porosity. Cu2+ cations compensating the charge of [PW12O40]3− in the as-synthesized material can be exchanged with cations such as Na+ and Eu3+. When exchanged with Eu3+, the material appears bright red under UV irradiation (see figure).

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