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Tao Zhang, Jun Gu, Yi Ding, Prof. Dr. Ya-Wen Zhang and Prof. Dr. Chun-Hua Yan Experimental and Theoretical Studies on the Controlled Synthesis of Alkali-Metal-Doped Rare-Earth Oxysulfide Nanocrystals ChemPlusChem 78

Version of Record online: 16 APR 2013 | DOI: 10.1002/cplu.201300092

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Making a difference: The doping alkali metal (Li, Na, K) was demonstrated to affect the size, morphology, composition, crystallinity, and luminescence properties of RE2O2S (RE=rare earth) ultrathin nanoplates (see figure) synthesized through thermolysis of metal acetylacetonates in hot surfactant in the presence of sublimed sulfur, as confirmed by both controlled experiments and first-principles calculations.

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