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Ioana Barbul, Dr. Andrew L. Johnson, Dr. Gabriele Kociok-Köhn, Prof. Kieran C. Molloy, Christian Silvestru and Dr. Anna L. Sudlow The Reaction and Materials Chemistry of [Sn6(O)4(OSiMe3)4]: Chemical Vapour Deposition of Tin Oxide ChemPlusChem 78

Article first published online: 2 JUL 2013 | DOI: 10.1002/cplu.201300104

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SnO flakes: Both [{Sn(OSiMe3)2}2] and [Sn6(O)4(OSiMe3)4] have been used as precursors for the chemical vapour deposition of SnO thin films (see figure). [{Sn(OSiMe3)2}2] reacts cleanly with O2 to form the mixed-valence cluster [Sn4(O)(OSiMe3)8].

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