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Guojian Chen, Dr. Yu Zhou, Pingping Zhao, Zhouyang Long and Prof. Dr. Jun Wang Mesostructured Dihydroxy-Functionalized Guanidinium-Based Polyoxometalate with Enhanced Heterogeneous Catalytic Activity in Epoxidation ChemPlusChem 78

Version of Record online: 26 APR 2013 | DOI: 10.1002/cplu.201300105

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IL effects: A self-assembled mesoporous polyoxometalate (POM) with coral-shaped morphology was obtained by pairing Keggin POM anions with newly designed dihydroxy-tethered guanidinium cations of an ionic liquid (IL). Enhancement of the heterogeneous catalytic activity in epoxidation is explained by a unique substrate–solvent–catalyst synergistic mechanism (see figure).

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