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S. R. Lingampalli, Uttam Gupta, Dr. Ujjal K. Gautam and Prof. C. N. R. Rao Oxidation of Toluene and Other Examples of C[BOND]H Bond Activation by CdO2 and ZnO2 Nanoparticles ChemPlusChem 78

Version of Record online: 20 JUN 2013 | DOI: 10.1002/cplu.201300114

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A select few: CdO2 and ZnO2 nanoparticles decompose to yield oxygen and metal oxide below 200 °C. Their use for the selective oxidation of the toluene CH3 group to yield mainly benzaldehyde in a catalyst-free reaction is demonstrated (see figure).

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