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Dr. Robert Kretschmer, Dr. Maria Schlangen and Prof. Dr. Helmut Schwarz Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations ChemPlusChem 78

Version of Record online: 19 JUN 2013 | DOI: 10.1002/cplu.201300138

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Ready, set, go! The reactions of cationic transition-metal hydroxides, [M(OH)]+, of the first row with ammonia have been studied both experimentally and computationally. With the exception of scandium, all ions investigated react predominantly under N[BOND]H bond activation (Cr–Ni, Zn), ligand exchange (Ni), or dehydrogenation (Ti, V). Regarding the efficiency, [Co(OH)]+ is taking a strong lead, followed by [Fe(OH)]+ and [Zn(OH)]+. Behind them are [Cr(OD)]+ and [Mn(OH)]+ while [Ti(OH)]+ and [V(OH)]+ ) are just one step behind.

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