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Yevhen Horbatenko and Prof. Sergei F. Vyboishchikov Si⋅⋅⋅H Interligand Interactions in Cobalt(V) and Iridium(V) Bis(silyl)bis(hydride) Complexes ChemPlusChem 78

Version of Record online: 16 JUL 2013 | DOI: 10.1002/cplu.201300174

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Studying the classics: Bis(silyl)bis(hydride) cobalt complexes [Cp*Co(H)2(SiR3)2] (Cp*=pentamethylcyclopentadienyl ligand) were found to possess interligand Si⋅⋅⋅H interactions of varying strength, whereas the analogous iridium complexes have classical structures (see figure).

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