Oliver Krahe, Prof. Dr. Frank Neese and Dr. Marianne Engeser Iron Azides with Cyclam-Derived Ligands: Are They Precursors for High-Valent Iron Nitrides in the Gas Phase? ChemPlusChem 78
High-valent iron nitrides: Azide complexes as their potential precursors are studied in the gas phase by mass spectrometry. A subtle interplay between pathways to FeII, FeIII, and FeV products is controlled by choice of the ligand (see figure). The observations partly parallel those seen after irradiating frozen solutions.
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