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Dr. Vincent Lemaur, Glenn Carroy, Frédéric Poussigue, Dr. Fabien Chirot, Dr. Julien De Winter, Prof. Lyle Isaacs, Dr. Philippe Dugourd, Dr. Jérôme Cornil and Prof. Pascal Gerbaux Homotropic Allosterism: In-Depth Structural Analysis of the Gas-Phase Noncovalent Complexes Associating a Double-Cavity Cucurbit[n]uril-Type Host and Size-Selected Protonated Amino Compounds ChemPlusChem 78

Article first published online: 8 JUL 2013 | DOI: 10.1002/cplu.201300208

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Molecular containers: Noncovalent complexes associating two size-selected protonated amino guests inside a double-cavity cucurbit[n]uril-type host are transferred from their acidic aqueous solutions to the gas phase upon electrospray ionization. Ion mobility spectroscopy coupled with mass spectrometry and combined with computational chemistry point to the conservation of the condensed-phase structure (see figure).

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