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Dr. Nianyuan Tan, Dr. Yi Chen, Dr. Yongbo Zhou, Prof. Dr. Chak-Tong Au and Prof. Dr. Shuang-Feng Yin Synthesis and Structure of Organobismuth Chlorides and Triflates Containing (C,E)-Chelating Ligands (E=O, S) and Their Catalytic Application in the Allylation of Aldehydes with Tetraallyltin ChemPlusChem 78

Version of Record online: 5 SEP 2013 | DOI: 10.1002/cplu.201300288

Thumbnail image of graphical abstract

Hyped up: Four air-stable hypervalent organobismuth compounds with (C,O)- or (C,S)-chelating ligands, R2BiCl (R=2-(MeECH2)C6H4; E=O, S), [2-(MeOCH2)C6H4]2BiOSO2CF3 (see picture) and [{2-(MeSCH2)C6H4}2Bi][OSO2CF3], have successfully been synthesized and characterized. The pictured compound shows excellent catalytic activity and reusability for the allylation of aldehydes with tetraallyltin.

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