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Prof. Yun Gong, Zhi Hao, Dr. Jiangping Meng, Huifang Shi, Penggang Jiang, Miaomiao Zhang and Prof. Jianhua Lin Two CoII Metal–Organic Frameworks Based on a Multicarboxylate Ligand as Electrocatalysts for Water Splitting ChemPlusChem 79

Article first published online: 8 NOV 2013 | DOI: 10.1002/cplu.201300334

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Water power: Based on 4,5-di(4′-carboxylphenyl)phthalic acid (H4L), two CoII complexes (see figure for topology) formulated as [Co4L2(4,4′-bpy)(H2O)6]3.5 H2O (4,4′-bpy=4,4′-bipyridine) and [Co2L(azene)(H2O)3]DMF (azene=(E)-1,2-di(pyridin-4-yl)diazene, DMF=dimethylformamide) both exhibit electrocatalytic activities toward generating H2 and O2 from water with lowered overpotentials and enhanced currents.

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