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V. P. Anju, Subrat Kumar Barik, Bijnaneswar Mondal, V. Ramkumar and Prof. Sundargopal Ghosh Metallaboranes from Metal Carbonyl Compounds and Their Utilization as Catalysts for Alkyne Cyclotrimerization ChemPlusChem 79

Version of Record online: 6 FEB 2014 | DOI: 10.1002/cplu.201400013

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Arachno­ compounds: Room-temperature UV photolysis of [Re2(CO)10] with BH3⋅thf yielded arachno-[(CO)8Re2B2H6], which catalyzed the cyclotrimerization of various internal and terminal alkynes to yield mixtures of 1,3,5- and 1,2,4-substituted benzenes (see figure).

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