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Charlie Van Doorslaer, Joos Wahlen, Pascal G. N. Mertens, Ben Thijs, Peter Nockemann, Koen Binnemans and Dirk E. De Vos Catalytic Hydrogenolysis of Aromatic Ketones in Mixed Choline–Betainium Ionic Liquids ChemSusChem 1

Article first published online: 28 NOV 2008 | DOI: 10.1002/cssc.200800140

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Mild, green fairy liquids: After screening a wide range of ionic liquids, a binary mixture of choline and betainium bis(trifluoromethylsulfonyl)imide ionic liquids was selected as the reaction medium for the hydrogenolysis of aromatic ketones. This mixture of ionic liquids functions both as co-catalyst and as immobilization medium for the palladium catalyst, which can efficiently be recycled after decantation of the reaction products.

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