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Bastien Léger, Audrey Denicourt-Nowicki, Hélène Olivier-Bourbigou and Alain Roucoux Rhodium Colloidal Suspensions Stabilised by Poly-N-donor Ligands in Non-Aqueous Ionic Liquids: Preliminary Investigation into the Catalytic Hydrogenation of Arenes ChemSusChem 1

Version of Record online: 28 NOV 2008 | DOI: 10.1002/cssc.200800194

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In a state of suspension: Colloidal suspensions of Rh0 nanoparticles stabilised by polynitrogen ligands such as 2,4,6-tris(2-pyridyl)-s-triazine were prepared in the ionic liquid l-n-butyl-3-methylimidazolium hexafluorophosphate ([BMI][PF6]) by chemical reduction of RhIII. The resulting suspensions of ligand-stabilised metallic nanoparticles were then applied as catalysts in the hydrogenation of arenes with excellent results.

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