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Tamao Ishida and Masatake Haruta N-Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles ChemSusChem 2

Article first published online: 12 MAY 2009 | DOI: 10.1002/cssc.200800260

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Dress code: formyl. Gold nanoparticles supported on NiO catalyze the one-pot N-formylation of amines with methanol and molecular oxygen to produce formamide at a selectivity of 90 %. This process generates methyl formate in situ, followed by reaction with amines.

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