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Aitor Gual, Cyril Godard, Karine Philippot, Bruno Chaudret, Audrey Denicourt-Nowicki, Alain Roucoux, Sergio Castillón and Carmen Claver Carbohydrate-Derived 1,3-Diphosphite Ligands as Chiral Nanoparticle Stabilizers: Promising Catalytic Systems for Asymmetric Hydrogenation ChemSusChem 2

Version of Record online: 13 JUL 2009 | DOI: 10.1002/cssc.200900079

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Metallic Ru, Rh, and Ir nanoparticles are prepared by the decomposition of organometallic precursors in the presence of 1,3-diphosphite ligands as stabilizing agents. These nanoparticles are shown to be active in the hydrogenation of m- and o-methylanisole.

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