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Dr. Shamindri M. Arachchige, Ryan Shaw, Travis A. White, Vimal Shenoy, Hei-Man Tsui and Prof. Karen J. Brewer High Turnover in a Photocatalytic System for Water Reduction to Produce Hydrogen Using a Ru, Rh, Ru Photoinitiated Electron Collector ChemSusChem 4

Article first published online: 22 MAR 2011 | DOI: 10.1002/cssc.201000399

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A robust photocatalytic system for the photochemical H2 production from H2O uses the single-component catalyst, [{(bpy)2Ru(dpp)}2RhBr2]5+. It functions at RT, in basic pH, and with significant H2 pressure, with its catalytic function being persistent for 50 h of photolysis. It provides 280 TONs in 19.5 h and 420 TONs in 50 h with a maximum ϕ=0.023 and an overall ϕ=0.014 for 19.5 h.

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