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Mathieu Baffert, Dr. Tarun K. Maishal, Laurent Mathey, Prof. Dr. Christophe Copéret  and Dr. Chloé Thieuleux Tailored Ruthenium–N-Heterocyclic Carbene Hybrid Catalytic Materials for the Hydrogenation of Carbon Dioxide in the Presence of Amine ChemSusChem 4

Article first published online: 22 NOV 2011 | DOI: 10.1002/cssc.201100223

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Hidden depths: Heterogeneous catalysts containing single-site ruthenium–bis-N-heterocyclic carbene (NHC) species are obtained by designing tailored hybrid organic–inorganic materials and in situ transformations, leading to final Ru-NHC units. These catalysts represent promising alternatives to homogeneous complexes with comparable activities (turnover number of ca. 3000).

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