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Thorsten vom Stein, Philipp M. Grande, Prof. Dr. Walter Leitner and Dr. Pablo Domínguez de María Iron-Catalyzed Furfural Production in Biobased Biphasic Systems: From Pure Sugars to Direct Use of Crude Xylose Effluents as Feedstock ChemSusChem 4

Version of Record online: 12 OCT 2011 | DOI: 10.1002/cssc.201100259

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Working with real samples: Aqueous solutions of FeCl3–NaCl (or seawater) dehydrate xylose to afford furfural, which can extracted in situ into 2-MTHF as second phase. Furfural is successfully obtained when aqueous nonpurified xylose effluents directly from lignocellulose fractionation are tested.

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