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Jianglin Hu, Prof. Yanlong Gu, Zhenhong Guan, Jinjin Li, Dr. Wanling Mo, Prof. Tao Li and Guangxing Li An Efficient Palladium Catalyst System for the Oxidative Carbonylation of Glycerol to Glycerol Carbonate ChemSusChem 4

Version of Record online: 16 NOV 2011 | DOI: 10.1002/cssc.201100337

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N Y Pd: A zeolite-Y-confined Pd catalyst, PdCl2(phen)@Y, enables the synthesis of glycerol carbonate by oxidative carbonylation of glycerol. Excellent conversion (95 %) and selectivity (98 %) are achieved with a very high glycerol-to-Pd molar ratio (2000). The catalyst can be re-used five times, without a significant decrease in activity and selectivity.

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