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Dr. Aziz Fihri, Dr. Dongkyu Cha, Dr. Mohamed Bouhrara, Noor Almana and Prof. Dr. Vivek Polshettiwar Fibrous Nano-Silica (KCC-1)-Supported Palladium Catalyst: Suzuki Coupling Reactions Under Sustainable Conditions ChemSusChem 5

Version of Record online: 15 NOV 2011 | DOI: 10.1002/cssc.201100379

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Noble amines recycled: Fibrous high-surface-area nano-silica functionalized with aminopropyl groups and loaded with well-dispersed Pd nanoparticles is evaluated for the Suzuki coupling of aromatic halides. It is active for the reaction of a range of aryl bromides and iodides as well as chlorides with aryl boronic acids in good to excellent yields. The catalyst can be recovered and reused for a number of cycles with negligible loss in activity.

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