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Jianglei Hu , Qingyin Wu, Wei Li, Ling Ma, Fang Su, Prof. Dr. Yihang Guo and Prof. Dr. Yongqing Qiu Epoxidation of Alkenes Catalyzed by Phenyl Group-Modified, Periodic Mesoporous Organosilica-Entrapped, Dimeric Manganese–Salen Complexes ChemSusChem 4

Article first published online: 22 NOV 2011 | DOI: 10.1002/cssc.201100382

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Manganese starts acting cagey: 3D cage-like, phenyl group-modified, periodic mesoporous organosilica-entrapped, dimeric manganese–salen complexes prepared by entrapment and silylation exhibit considerably higher catalytic activity and stability towards the epoxidation of alkenes than their monomeric analogues and the starting homogeneous dimeric manganese–salen complexes.

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