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Dr. Yoichi M. A. Yamada, Dr. Toshihiro Watanabe, Aya Ohno and Prof. Dr. Yasuhiro Uozumi Development of Polymeric Palladium-Nanoparticle Membrane-Installed Microflow Devices and their Application in Hydrodehalogenation ChemSusChem 5

Article first published online: 13 JAN 2012 | DOI: 10.1002/cssc.201100418

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Streamlined nanoparticles: We developed a variety of polymeric Pd nanoparticle membrane-installed microflow devices. Instantaneous hydrodehalogenation of aryl halides can be achieved at short residence times and moderate temperatures using a safe, nonexplosive aqueous sodium formate to quantitatively afford the corresponding hydrodehalogenated products. PCB and PBB can also be fully decomposed under similar conditions to give a biphenyl.

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