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Prof. Carmela Aprile, Dr. Francesco Giacalone, Paola Agrigento, Dr. Leonarda F. Liotta, Prof. Johan A. Martens, Prof. Paolo P. Pescarmona and Prof. Michelangelo Gruttadauria Multilayered Supported Ionic Liquids as Catalysts for Chemical Fixation of Carbon Dioxide: A High-Throughput Study in Supercritical Conditions ChemSusChem 4

Version of Record online: 23 NOV 2011 | DOI: 10.1002/cssc.201100446

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An epoxcellent discovery: Multilayered, covalently supported ionic liquid phase (mlc-SILP) materials are successfully prepared and used as catalysts for the cycloaddition of carbon dioxide to epoxides, yielding cyclic carbonates. The materials are highly active, show improved productivity compared to known supported ionic liquid catalysts, and can be easily recovered and reused without loss of activity.

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