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Marcel Risch, Katharina Klingan, Franziska Ringleb, Dr. Petko Chernev, Dr. Ivelina Zaharieva, Dr. Anna Fischer and Prof. Dr. Holger Dau Water Oxidation by Electrodeposited Cobalt Oxides—Role of Anions and Redox-Inert Cations in Structure and Function of the Amorphous Catalyst ChemSusChem 5

Version of Record online: 9 FEB 2012 | DOI: 10.1002/cssc.201100574

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Cobalt crowds crack it up: The catalytic activity of a cobalt-oxido film for water oxidation may be inversely proportional to atomic order, determined by the size of contiguous CoxOy clusters in the amorphous material. The redox-inert cations and anions in CoCat modulate redox properties and catalytic activity without modifying the basic structural motif of Co-oxido clusters.

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