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Prof. Pedro Lozano, Prof. Eduardo García-Verdugo, Juana M. Bernal, Diana F. Izquierdo, Prof.  M. Isabel Burguete, Prof. Gregorio Sánchez-Gómez and Prof. Santiago V. Luis Immobilised Lipase on Structured Supports Containing Covalently Attached Ionic Liquids for the Continuous Synthesis of Biodiesel in scCO2 ChemSusChem 5

Article first published online: 1 MAR 2012 | DOI: 10.1002/cssc.201100692

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Enzyme catalysis goes critical:Candida antarctica lipase B has been immobilised on different polymeric matrices containing a covalently attached ionic liquid phase. A continuous biocatalytic process for biodiesel synthesis has been successfully carried out in supercritical CO2 for 45 operational cycles with excellent enzyme activity and stability. Appropriate selection of the IL results in a clear improvement of the efficiency for the biotransformation.

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