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Dr. Yasutaka Kuwahara, Keita Tsuji, Dr. Tetsutaro Ohmichi, Dr. Takashi Kamegawa, Dr. Kohsuke Mori and Prof. Dr. Hiromi Yamashita Waste-Slag Hydrocalumite and Derivatives as Heterogeneous Base Catalysts ChemSusChem 5

Version of Record online: 22 JUN 2012 | DOI: 10.1002/cssc.201100814

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All your slag are belong to us: A Ca-based layered double hydroxide, hydrocalumite, and its derivatives synthesized from waste iron-making slag are useful heterogeneous base catalysts for multiple chemical reactions, including the Knoevenagel condensation, the oxidation of alkylaromatics with O2, transesterification, and CO2 fixation (see scheme). Slag-derived impurities effectively act either as active sites or catalyst promoters.

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