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Sung Min Kim and Prof. Seong Ihl Woo Sustainable Production of Syngas from Biomass-Derived Glycerol by Steam Reforming over Highly Stable Ni/SiC ChemSusChem 5

Version of Record online: 29 JUN 2012 | DOI: 10.1002/cssc.201100821

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Steam-reforming of biomass-derived glycerol is important sustainable production of fuels and chemicals. Neutral SiC promotes intrinsic nickel contributions, dehydrogenation and decarbonylation, without the deactivation caused by coke deposition and side reactions, such as dehydrationand condensation. Nonoxide SiC is less active in the water–gas-shift reaction than the oxide supports Al2O3 and CeO2. Syngas with a H2/CO ratio of approximately 2.0 can be produced over Ni/SiC.

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