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Dr. Francesco Barzagli, Prof. Massimo Di Vaira, Prof. Fabrizio Mani and Dr. Maurizio Peruzzini Improved Solvent Formulations for Efficient CO2 Absorption and Low-Temperature Desorption ChemSusChem 5

Article first published online: 9 JUL 2012 | DOI: 10.1002/cssc.201200062

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Clean up your flue: CO2 capture by 2-amino-2-methyl-1-propanol (AMP)/amine blends in organic solvents is investigated in a packed-bed reactor operating continuously, and the carbonated species in solution are analyzed by using in situ 13C NMR spectroscopy. Solid AMP carbamate and AMPH+ carbonate, structurally characterized by XRD, react with some alcohols to afford the corresponding alkyl carbonates.

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