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Arianna Savini, Prof. Gianfranco Bellachioma, Prof. Dr. Sandra Bolaño, Dr. Luca Rocchigiani, Dr. Cristiano Zuccaccia, Dr. Daniele Zuccaccia and Prof. Dr. Alceo Macchioni Iridium-EDTA as an Efficient and Readily Available Catalyst for Water Oxidation ChemSusChem 5

Version of Record online: 11 JUL 2012 | DOI: 10.1002/cssc.201200067

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It′s so easy: The readily available and highly water-soluble [IrCl(Hedta)]Na complex is an efficient and robust catalyst for water oxidation to molecular oxygen. The reaction is driven by the reduction of Ce4+ to Ce3+. Its performances (TOF=6.8 min−1 and TON>12 000) are derived by UV/Vis spectroscopic, volumetric and electrochemical measurements, and compare favorably with those of the best catalysts reported so far.

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