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Dr. Elżbieta Skrzyńska, Jamal Ftouni, Dr. Jean-Sébastien Girardon, Dr. Mickaël Capron, Dr. Louise Jalowiecki-Duhamel, Prof. Jean-François Paul and Prof. Franck Dumeignil Quasi-Homogeneous Oxidation of Glycerol by Unsupported Gold Nanoparticles in the Liquid Phase ChemSusChem 5

Article first published online: 7 AUG 2012 | DOI: 10.1002/cssc.201200173

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Getting the balance right: The product distribution observed during the liquid-phase partial oxidation reaction of glycerol is discussed in terms of balance between reactions specifically induced by the presence of a base in the medium and reactions as a result of the specific action of gold nanoparticles as catalyst (see figure). A global reaction scheme supported by a set of mechanistic analyses is proposed.

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